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Catal. Sci. Technol., 2016, Advance Article
DOI: 10.1039/C5CY01883H, Paper
DOI: 10.1039/C5CY01883H, Paper
Stefan Christiaan Stouten, Timothy Noel, Qi Wang, Matthias Beller, Volker Hessel
The methoxycarbonylation of cyclohexene with carbon dioxide over a ruthenium catalyst was realized in a micro flow system under supercritical conditions.
The methoxycarbonylation of cyclohexene with carbon dioxide over a ruthenium catalyst was realized in a micro flow system under supercritical conditions.
Continuous ruthenium-catalyzed methoxycarbonylation with supercritical carbon dioxide
The methoxycarbonylation of cyclohexene with carbon dioxide over a ruthenium catalyst was realized in a micro flow system under supercritical conditions. Instead of the toxic and flammable carbon monoxide, this process utilizes carbon dioxide, thereby avoiding issues with bulk transportation of carbon monoxide as well as eliminating the need for safety precautions associated with the use of carbon monoxide. Obtained was a 77% yield of the ester product at 180 °C, 120 bar and with a 90 min residence time, which is over five times faster than for the same reaction performed under subcritical conditions in batch. An important factor for the performance of the system was to have a sufficiently polar supercritical mixture, allowing the catalyst to dissolve well. The optimal temperature for the reaction was 180 °C, as the activity of the system dropped considerably at higher temperatures, most likely due to catalyst deactivation.
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Department of Chemical Engineering and Chemistry
ir. S.C. (Stefan) Stouten –
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Address:
Technische Universiteit Eindhoven
P.O. Box 513
5600 MB EINDHOVEN
P.O. Box 513
5600 MB EINDHOVEN
- Department:
- Department of Chemical Engineering and Chemistry
- Section:
- Micro Flow Chemistry and Process Technology
- Positioncategory:
- doctoral candidate (PhD) (PhD Stud.)
- Position:
- doctoral candidate
- Room:
- STW 0.
- Email:
- s.stouten@tue.nl
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Volker Hessel
prof.dr. V. (Volker) Hessel
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Address:
Technische Universiteit Eindhoven
P.O. Box 513
5600 MB EINDHOVEN
P.O. Box 513
5600 MB EINDHOVEN
Chair:
Micro Flow Chemistry and Process Technology
- Department:
- Department of Chemical Engineering and Chemistry
- Section:
- Micro Flow Chemistry and Process Technology
- Positioncategory:
- Professor (HGL)
- Position:
- Full Professor
- Room:
- STW 1.45
- Tel:
- +31 40-247 2973
- Tel (internal):
- 2973
- Email:
- v.hessel@tue.nl
////////Continuous, ruthenium-catalyzed, methoxycarbonylation, supercritical carbon dioxide, flow reactor
Filed under: PROCESS, SYNTHESIS Tagged: Continuous, flow reactor, Matthias Beller, methoxycarbonylation, Qi Wang, ruthenium-catalyzed, Stefan Christiaan Stouten, supercritical carbon dioxide, Technische Universiteit Eindhoven, Timothy Noel, Volker Hessel Image may be NSFW.
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