*Corresponding authors
aFriedrich-Alexander University Erlangen-Nürnberg, Department of Organic Chemistry I, Henkestraße 42, 91054 Erlangen, Germany
Green Chem., 2015, Advance Article
DOI: 10.1039/C5GC00794A
Ina Hoffmann, Bettina Blumenroder, Silvia Onodi nee Thumann, Sabine Dommer, Jurgen Schatz
Efficient and generally applicable ligand-less and ligand-supported Suzuki coupling reactions in pure water under aerobic conditions.
Efficient and generally applicable ligand-less and ligand-supported Suzuki coupling reactions in pure water under aerobic conditions.
We report a simple and efficient procedure for the ligand-free as well as ligand-assisted Suzuki reaction in both pure water and aqueous media. The cross-coupling reactions proceed successfully using phenylboronic acid or potassium phenyltrifluoroborate as a nucleophilic coupling partner. The method can be effectively applied to both activated and deactivated aryl halides yielding quantitative conversions…
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